Tetraruthenium Macrocycles with Laterally Extended Bis(alkenyl)quinoxaline Ligands and Their F4TCNQ•− Salts
نویسندگان
چکیده
We report on the tetraruthenium macrocycles Ru4-5 and -6 with a π-conjugated pyrene-appended 5,8-divinylquinoxaline ligand either isophthalate or thiophenyl-2,5-dicarboxylate linkers their charge-transfer salts formed by oxidation two equivalents of F4TCNQ. Both macrocyclic complexes were characterized NMR spectroscopy, mass spectrometry, cyclic square-wave voltammetry, IR, UV–vis–NIR, EPR spectroscopy in various states.
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ژورنال
عنوان ژورنال: Inorganics (Basel)
سال: 2022
ISSN: ['2304-6740']
DOI: https://doi.org/10.3390/inorganics10060082